Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.006 A Ê R factor = 0.040 wR factor = 0.062 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Poly[(μ3-acetylenedicarboxylato-κ4O,O′:O′′:O′′′)(1,10-phenanthroline-κ2N,N′)cadmium(II)]
✍ Scribed by Wang, Huan-Yu ;Gao, Shan ;Huo, Li-Hua ;Zhao, Jing-Gui
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 572 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
2 N,N 0 0 0 )cadmium(II)]-l 3pyridine-3,4-dicarboxylato-j 5 N:O,O 0 0 0 :O 0 0 00 0 0 ,O 0 0 00 0 00 0
The title complex, [Cd(C 6 H 4 NO 2 ) 2 (C 12 H 8 N 2 )] n , is a onedimensional chain-like coordination polymer. Adjacent chains are further aggregated into a three-dimensional network through -(interplanar distance is 3.5806 A ˚) and C-HÁ Á Á interactions.
The Cd^II^ atom in the title complex, [Cd(C~8~H~5~O~3~)~2~(C~12~H~8~N~2~)(H~2~O)], is coordinated by three O atoms of two formylbenzoate ligands, two N atoms of a 1,10-phenanthroline ligand and one water molecule, giving rise to a trigonal–prismatic coordination geometry. Adjacent complex molecules
In the title polymeric complex, [Cd(C 4 H 2 O 4 )(C 12 H 8 N 2 )-(H 2 O) 2 ] n , the Cd II ions are bridged by fumarate dianions to form zigzag complex chains.stacking is observed between the parallel phenanthroline ligands of neighboring complex chains. The Cd ion is located on a twofold axis and h
The title compound, {[Co(C 8 H 4 O 5 )(C 12 H 8 N 2 )]ÁH 2 O} n , is isostructural with its manganese analog [Skakle, Foreman & Plater (2001). Acta Cryst. E57, m373±m375]. The asymmetric unit consists of one Co atom, one 1,10-phenanthroline ligand bound in a bidentate manner, one hydroxyisophthalate