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Poly­[[[(1,10-phenanthroline-κ2N,N′)­cobalt(II)]-μ3-5-hydroxy­isophthalato-κ4O,O′:O′′:O′′′] monohydrate]

✍ Scribed by Cao, Xin-Yi ;Zhang, Jian ;Kang, Yao ;Cheng, Jian-Kai ;Li, Zhao-Ji ;Wang, Xiao-Qin ;Yao, Yuan-Gen

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
334 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, {[Co(C 8 H 4 O 5 )(C 12 H 8 N 2 )]ÁH 2 O} n , is isostructural with its manganese analog [Skakle, Foreman & Plater (2001). Acta Cryst. E57, m373±m375]. The asymmetric unit consists of one Co atom, one 1,10-phenanthroline ligand bound in a bidentate manner, one hydroxyisophthalate ligand and one water molecule. The Co coordination is completed by two further O atoms from two symmetry-related hydroxyisophthalate ligands, giving a grossly distorted octahedral geometry.

📜 SIMILAR VOLUMES

Poly[[[(2,2′-bipyridine-κ2N,N′)cobalt(II
Poly[[[(2,2′-bipyridine-κ2N,N′)cobalt(II)]-μ3-5-hydroxy­isophthalato-κ4O,O′:O′′:O′′′] dihydrate]
✍ Zhuo, Xin ;Pan, Zhao-Rui ;Wang, Zuo-Wei ;Li, Yi-Zhi ;Zheng, He-Gen 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 504 KB

In the title compound, {[Co(C~8~H~4~O~5~)(C~10~H~8~N~2~)]·2H~2~O]}~__n__~ or {[Co(OH-BDC)(2,2′-bipy)]·2H~2~O]}~__n__~ (where OH-H~2~BDC is 5-hydroxyisophthalic acid and 2,2′-bipy is 2,2′-bipyridine), the Co atoms are chelated by two N atoms from the 2,2′-bipy ligand and by four O atoms from OH-BDC l