The asymmetric unit of the title compound, [Sn(C 4 H 9 ) 3 -(C 6 H 4 NO 2 )] n , consists of three butyl and one pyridine-3carboxylate groups bonded to the Sn atom in a distorted trigonal-bipyramidal geometry. In the crystal structure, these units are linked to form an infinite one-dimensional polym
catena-Poly[[(1,10-phenanthroline-κ2N,N′)(pyridine-3-carboxylato-κ2O:O′)cadmium(II)]-μ-pyridine-3-carboxylato-κ3N:O,O′]
✍ Scribed by Yi, Hong-Chao ;Mei, Ping
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 553 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title complex, [Cd(C 6 H 4 NO 2 ) 2 (C 12 H 8 N 2 )] n , is a onedimensional chain-like coordination polymer. Adjacent chains are further aggregated into a three-dimensional network through -(interplanar distance is 3.5806 A ˚) and C-HÁ Á Á interactions.
📜 SIMILAR VOLUMES
2 N,N 0 0 0 )cadmium(II)]-l 3pyridine-3,4-dicarboxylato-j 5 N:O,O 0 0 0 :O 0 0 00 0 0 ,O 0 0 00 0 00 0
The title compound, [Mn(C 5 H 3 N 2 O 2 ) 2 (H 2 O)] n , prepared by hydrothermal synthesis, is isostructural with its Fe II , Co II , Ni II and Cu II analogues. The asymmetric unit contains two bidendate pyrazine-2-carboxylate anions coordinated to Mn II in the equatorial plane through one N and on
Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.006 A Ê R factor = 0.040 wR factor = 0.062 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.