In the title polymeric complex, [Cd(C 4 H 2 O 4 )(C 12 H 8 N 2 )-(H 2 O) 2 ] n , the Cd II ions are bridged by fumarate dianions to form zigzag complex chains.stacking is observed between the parallel phenanthroline ligands of neighboring complex chains. The Cd ion is located on a twofold axis and h
catena-Poly[[1,10-phenanthroline-κ2N,N′)cadmium(II)]-μ-3,5-dimethylbenzoato-κ2O:O′]
✍ Scribed by Chen, Man-Sheng ;Zhang, Chun-Hua ;Kuang, Dai-Zhi ;Feng, Yong-Lan ;Deng, Yi-Fang
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 156 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.006 A Ê R factor = 0.040 wR factor = 0.062 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Bis(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10-phenanthrolinej 2 N,N 0 0 0 )cadmium(II)-bis(l 2 -4-formylbenzoatoj 2 O:O 0 0 0 )bis[(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10phenanthroline-j 2 N,N 0 0 0 )cadmium(II)] (1/1
The title complex, [Cd(C 6 H 4 NO 2 ) 2 (C 12 H 8 N 2 )] n , is a onedimensional chain-like coordination polymer. Adjacent chains are further aggregated into a three-dimensional network through -(interplanar distance is 3.5806 A ˚) and C-HÁ Á Á interactions.