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Aqua­bis(benzimidazole-κN)bis­(4-formyl­benzoato)-κO;κ2O,O′-cadmium(II) tetra­hydrate

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
138 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the title compound, [Cd(C 7 H 5 O 3 ) 2 (C 7 H 6 N 2 ) 2 ]ÁH 2 O, the Cd II ion is surrounded by two salicylate anions and two benzimidazole molecules in a strongly distorted octahedral cis-CdN 2 O 4 geometry. The partially overlapped arrangement and the face-to-face distances of 3.22 (3) and 3.3

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The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral co