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μ-Aqua-bis­(μ-4-methyl­benzoato-κ2O:O′)bis[(4-methyl­benzoato-κO)(phenanthroline-κ2N,N′)cobalt(II)]

✍ Scribed by Zhang, Bing-Yu ;Xu, Tu-Gen ;Xu, Duan-Jun

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
379 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral coordination geometry. -Stacking occurs between roughly parallel MBZ and phenanthroline (phen) ligands and between parallel phen ligands. metal-organic papers m2188 Zhang et al. [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 (H 2 O)]

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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.037 wR factor = 0.091 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.