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Bis(μ-4-formyl­benzoato)-κ3O,O′:O′;κ3O:O,O′-bis­[(4-formyl­benzoato-κ2O,O′)(imidazole-κN)cadmium(II)] dihydrate

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
128 KB
Volume
62
Category
Article
ISSN
1600-5368

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The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral co

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The Co atom of the title compound, [Co(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 -(H 2 O) 2 ], which lies on a centre of inversion, is coordinated by two imidazole and two water molecules, as well as by formylbenzoate groups, in an all-trans octahedral geometry.