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Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)cobalt(II)

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
116 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The Co atom of the title compound, [Co(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 -(H 2 O) 2 ], which lies on a centre of inversion, is coordinated by two imidazole and two water molecules, as well as by formylbenzoate groups, in an all-trans octahedral geometry.

📜 SIMILAR VOLUMES

Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-
Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)nickel(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 129 KB

The title compound, [Ni(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is isostructural with the manganese analogue. The Ni atom, which lies on a centre of inversion, is coordinated by two imidazole and two water ligands, as well as by the formylbenzoate groups, in an all-trans octahedral geometry.

Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-
Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)manganese(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 135 KB

The Mn atom in the title compound, [Mn(C 8 H 5 O 3 ) 2 -(C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is datively linked to the imidazole heterocycles and water molecules, and covalently linked to the substituted benzoate groups in an all-trans octahedral geometry; the Mn atom lies on a center of inversion.

Di­aqua­bis(1H-imidazole-κN3)­bis(4-nitr
Di­aqua­bis(1H-imidazole-κN3)­bis(4-nitro­benzoato-κO)­cobalt(II)
✍ Xu, Tu-Gen ;Xu, Duan-Jun 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 288 KB

Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.025 wR factor = 0.066 Data-to-parameter ratio = 11.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Aqua­bis(1H-imidazole-κN3)bis­(4-methyl­
Aqua­bis(1H-imidazole-κN3)bis­(4-methyl­benzoato-κ2O,O′)cobalt(II)
✍ Song, Wen-Dong ;Gu, Chang-Sheng ;Hao, Xiao-Min ;Liu, Ji-Wei 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 220 KB

The Co II centre in the title complex, [Co(C 8 H 7 O 2 ) 2 (C 3 H 4 N 2 ) 2 -(H 2 O)], has a distorted octahedral coordination geometry, involving three O atoms derived from two 4-methylbenzoate ligands, two N atoms from the imidazole ligands and a water molecule. Intermolecular O-HÁ Á ÁO and N-HÁ Á