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Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)nickel(II)

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
129 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Ni(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is isostructural with the manganese analogue. The Ni atom, which lies on a centre of inversion, is coordinated by two imidazole and two water ligands, as well as by the formylbenzoate groups, in an all-trans octahedral geometry.

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Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-
Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)cobalt(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 116 KB

The Co atom of the title compound, [Co(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 -(H 2 O) 2 ], which lies on a centre of inversion, is coordinated by two imidazole and two water molecules, as well as by formylbenzoate groups, in an all-trans octahedral geometry.

Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-
Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)manganese(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 135 KB

The Mn atom in the title compound, [Mn(C 8 H 5 O 3 ) 2 -(C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is datively linked to the imidazole heterocycles and water molecules, and covalently linked to the substituted benzoate groups in an all-trans octahedral geometry; the Mn atom lies on a center of inversion.

Diaqua­bis(4-formyl­benzoato-κO)zinc(II)
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✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 282 KB

Single-crystal X-ray study T = 295 K Mean (C-C) = 0.002 A R factor = 0.026 wR factor = 0.074 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis(1H-imidazole-κN3)­bis(3-methyl­benzo
Bis(1H-imidazole-κN3)­bis(3-methyl­benzoato-κO)copper(II)
✍ Xu, Tu-Gen ;Liu, Jia-Geng ;Xu, Duan-Jun 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 301 KB

In the title complex, [Cu(C 8 H 7 O 2 ) 2 (C 3 H 4 N 2 ) 2 ], the Cu II atom, located on an inversion center, has a square-planar coordination geometry formed by imidazole molecules and 3methylbenzoate anions. Hydrogen-bonding and C-HÁ Á Á interactions occur between imidazole and methylbenzoate liga