𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis(1H-imidazole-κN3)­bis(3-methyl­benzoato-κO)copper(II)

✍ Scribed by Xu, Tu-Gen ;Liu, Jia-Geng ;Xu, Duan-Jun

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
301 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title complex, [Cu(C 8 H 7 O 2 ) 2 (C 3 H 4 N 2 ) 2 ], the Cu II atom, located on an inversion center, has a square-planar coordination geometry formed by imidazole molecules and 3methylbenzoate anions. Hydrogen-bonding and C-HÁ Á Á interactions occur between imidazole and methylbenzoate ligands of neighboring complex molecules.

📜 SIMILAR VOLUMES

Aqua­bis(1H-imidazole-κN3)bis­(4-methyl­
Aqua­bis(1H-imidazole-κN3)bis­(4-methyl­benzoato-κ2O,O′)cobalt(II)
✍ Song, Wen-Dong ;Gu, Chang-Sheng ;Hao, Xiao-Min ;Liu, Ji-Wei 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 220 KB

The Co II centre in the title complex, [Co(C 8 H 7 O 2 ) 2 (C 3 H 4 N 2 ) 2 -(H 2 O)], has a distorted octahedral coordination geometry, involving three O atoms derived from two 4-methylbenzoate ligands, two N atoms from the imidazole ligands and a water molecule. Intermolecular O-HÁ Á ÁO and N-HÁ Á

Bis(1H-imidazole-κN3)bis­(4-methyl­benzo
Bis(1H-imidazole-κN3)bis­(4-methyl­benzoato-κO)zinc(II) 4-methyl­benzoic acid disolvate
✍ Gu, Chang-Sheng ;Hao, Xiao-Min ;Song, Wen-Dong ;Yan, Jian-Bin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 275 KB

The molecular structure of the title compound, [Zn(C~8~H~7~O~2~)~2~(C~7~H~6~N~2~)~2~]·2C~8~H~8~O~2~, is composed of a mononuclear Zn^II^ complex, which possesses twofold rotation symmetry, and two uncoordinated 4-methylbenzoic acid molecules. The Zn^II^ atom displays a four-coordinate distorted tetr

Di­aqua­bis(1H-imidazole-κN3)­bis­(nitro
Di­aqua­bis(1H-imidazole-κN3)­bis­(nitro­benzoato-κO)­manganese(II)
✍ Xu, Tu-Gen ;Xu, Duan-Jun 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 259 KB

Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.031 wR factor = 0.082 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-
Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)cobalt(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 116 KB

The Co atom of the title compound, [Co(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 -(H 2 O) 2 ], which lies on a centre of inversion, is coordinated by two imidazole and two water molecules, as well as by formylbenzoate groups, in an all-trans octahedral geometry.

Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-
Diaqua­bis(4-formyl­benzoato-κO)bis­(1H-imidazole-κN3)nickel(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 129 KB

The title compound, [Ni(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 (H 2 O) 2 ], is isostructural with the manganese analogue. The Ni atom, which lies on a centre of inversion, is coordinated by two imidazole and two water ligands, as well as by the formylbenzoate groups, in an all-trans octahedral geometry.