Aquabis(1H-imidazole-κN3)bis(4-methylbenzoato-κ2O,O′)cobalt(II)
✍ Scribed by Song, Wen-Dong ;Gu, Chang-Sheng ;Hao, Xiao-Min ;Liu, Ji-Wei
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 220 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The Co II centre in the title complex, [Co(C 8 H 7 O 2 ) 2 (C 3 H 4 N 2 ) 2 -(H 2 O)], has a distorted octahedral coordination geometry, involving three O atoms derived from two 4-methylbenzoate ligands, two N atoms from the imidazole ligands and a water molecule. Intermolecular O-HÁ Á ÁO and N-HÁ Á ÁO hydrogen bonds along withstacking interactions give rise to a layer structure.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.025 wR factor = 0.066 Data-to-parameter ratio = 11.6 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral co
The Co atom of the title compound, [Co(C 8 H 5 O 3 ) 2 (C 3 H 4 N 2 ) 2 -(H 2 O) 2 ], which lies on a centre of inversion, is coordinated by two imidazole and two water molecules, as well as by formylbenzoate groups, in an all-trans octahedral geometry.
In the title complex, [Cu(C 8 H 7 O 2 ) 2 (C 3 H 4 N 2 ) 2 ], the Cu II atom, located on an inversion center, has a square-planar coordination geometry formed by imidazole molecules and 3methylbenzoate anions. Hydrogen-bonding and C-HÁ Á Á interactions occur between imidazole and methylbenzoate liga
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.031 wR factor = 0.082 Data-to-parameter ratio = 11.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.