Tetraaquabis(4-formylbenzoato-κO)nickel(II) tetrahydrate
✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 123 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title Mn^II^ complex, [Mn(C~9~H~10~NO~2~)~2~(H~2~O)~4~]·2H~2~O, is monomeric and centrosymmetric. It contains two 4-dimethylaminobenzoate ligands, four coordinated and two uncoordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom fo
The Mn atom in the title compound, [Mn(C~12~H~8~NO~2~)~2~(H~2~O)~4~], lies on a centre of inversion in an all-__trans__-N~2~O~4~Mn octahedron; as the 4-(4-pyridyl)benzoate ligands bind to Mn through the pyridyl N atom, the compound is formally a zwitterion. Hydrogen bonds link adjacent zwitterions i