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Tetra­aqua­bis[4-(dimethyl­amino)benzoato-κO]manganese(II) dihydrate

✍ Scribed by Hökelek, Tuncer ;Necefoğlu, Hacali

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
177 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title Mn^II^ complex, [Mn(C~9~H~10~NO~2~)~2~(H~2~O)~4~]·2H~2~O, is monomeric and centrosymmetric. It contains two 4-dimethylaminobenzoate ligands, four coordinated and two uncoordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom form a slightly distorted square-planar arrangement, while the distorted octahedral coordination is completed by the two water O atoms in the axial positions. In the crystal structure, intra- and intermolecular O—H...O hydrogen bonds link the molecules into chains.

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