The Cd^II^ ion of the title mononuclear complex, [Cd(C~12~H~9~O~2~)~2~(C~7~H~6~N~2~)~2~]·H~2~O, lies on a crystallographic twofold rotation axis and is in a distorted trigonal prismatic coordination enivironment, involving four carboxylate O atoms from two chelating naphthaleneacetate ligands and tw
Bis(benzimidazole-κN)bis(salicylato-κ2O,O′)cadmium(II) monohydrate
✍ Scribed by Fu, Xiao-Du ;Lin, Dong-Dong ;Xu, Duan-Jun
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 521 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, [Cd(C 7 H 5 O 3 ) 2 (C 7 H 6 N 2 ) 2 ]ÁH 2 O, the Cd II ion is surrounded by two salicylate anions and two benzimidazole molecules in a strongly distorted octahedral cis-CdN 2 O 4 geometry. The partially overlapped arrangement and the face-to-face distances of 3.22 (3) and 3.34 (2) A suggest stacking between the benzimidazole ligands of neighbouring molecules.
📜 SIMILAR VOLUMES
In the title compound, (C~4~H~7~N~2~)~2~[Mn(C~7~H~4~O~3~)~2~(C~4~H~6~N~2~)~2~] [Mn(C~7~H~4~O~3~)~2~(CH~4~O)~2~]·2CH~4~O, there are two independent Mn^III^ ions, each located on an inversion center. The two Mn^III^ ions assume a distorted octahedral geometry and the complex anions are hydrogen bonded
In the mononuclear title compound, [Cd(C~8~H~5~O~3~)~2~(C~10~H~8~N~2~)(H~2~O)]·H~2~O, the Cd atom is __O__,__O__′-chelated by two 4-formylbenzoate monoanions and __N__,__N__′-chelated by 2,2′-bipyridine. It is also coordinated by a water molecule in a monocapped trigonal-prismatic geometry. The coor