l-Adipato-j 4 O,O 0 0 0 :O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(2,9dimethyl-1,10-phenanthroline-j 2 N,N)nitratocadmium(II)] dihydrate
μ-Adipato-κ4O,O′;O′′,O′′′-bis[chloro(2,9-dimethyl-1,10-phenanthroline-κ2N,N)copper(II)] dihydrate
✍ Scribed by Du, Fang-Lin ;Ding, Cai-Feng ;Zhu, Mei ;Li, Xue-Mei ;Zhang, Shu-Sheng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 309 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
l-Adipato-j 4 O,O 0 0 0 ;O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[chloro(2,9dimethyl-1,10-phenanthroline-j 2 N,N)copper(II)] dihydrate
📜 SIMILAR VOLUMES
In the title dimeric complex, [Cu~2~(C~2~O~4~)Cl~2~(C~12~H~8~N~2~)~2~], which lies on a crystallographic inversion center, the Cu^II^ ion is in a distorted trigonal–bipyramidal coordination geometry formed by two N atoms from a phen ligand, two O atoms from a bridging oxalate ligand and one Cl atom.
In the title compound, [Mn(C~7~H~5~O~3~)~2~(C~14~H~12~N~2~)]·C~14~H~12~N~2~·2H~2~O, the Mn^II^ ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by O—H...O a
l 2 -Oxalato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)] dinitrate dihydrate
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h