Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.039 wR factor = 0.087 Data-to-parameter ratio = 15.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Bis(glycolato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)copper(II) dihydrate
✍ Scribed by Du, Lin ;Zhang, Yu-Hua ;Fang, Rui-Bing ;Zhao, Qi-Hua
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 236 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions help to consolidate the crystal packing.
📜 SIMILAR VOLUMES
l 2 -Oxalato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)] dinitrate dihydrate
In the title compound, [Mn(C~7~H~5~O~3~)~2~(C~14~H~12~N~2~)]·C~14~H~12~N~2~·2H~2~O, the Mn^II^ ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by O—H...O a