Bis(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10-phenanthrolinej 2 N,N 0 0 0 )cadmium(II)-bis(l 2 -4-formylbenzoatoj 2 O:O 0 0 0 )bis[(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10phenanthroline-j 2 N,N 0 0 0 )cadmium(II)] (1/1
Bis(4-hydroxybenzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)copper(II)
✍ Scribed by Su, Jian-Rong ;Gu, Jian-Ming ;Xu, Duan-Jun
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 364 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.037 wR factor = 0.091 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The two independent molecules of the title compound, [Ba(C~7~H~5~O~3~)~2~(C~12~H~8~N~2~)~2~(H~2~O)~2~], are disposed about a pseudo-inversion centre. The Ba atom is eight-coordinate in a square-antiprismatic geometry in both molecules.
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h
The title complex, [Co(C 7 H 5 O 3 ) 2 (C 12 H 8 N 2 )(H 2 O) 2 ]ÁH 2 O, displays a distorted octahedral coordination geometry about the Co II atom, involving two 4-hydroxybenzoate anions, one 1,10-phenanthroline (phen) molecule and two water molecules. The face-to-face distance of 3.420 (5) A ˚betw