Diaquabis(3-hydroxybenzoato-κO)bis(1,10-phenanthroline-κ2N,N′)barium(II)
✍ Scribed by Liu, Ji-Wei ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 255 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The two independent molecules of the title compound, [Ba(C~7~H~5~O~3~)~2~(C~12~H~8~N~2~)~2~(H~2~O)~2~], are disposed about a pseudo-inversion centre. The Ba atom is eight-coordinate in a square-antiprismatic geometry in both molecules.
📜 SIMILAR VOLUMES
Bis(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10-phenanthrolinej 2 N,N 0 0 0 )cadmium(II)-bis(l 2 -4-formylbenzoatoj 2 O:O 0 0 0 )bis[(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10phenanthroline-j 2 N,N 0 0 0 )cadmium(II)] (1/1
The title complex, [Co(C 7 H 5 O 3 ) 2 (C 12 H 8 N 2 )(H 2 O) 2 ]ÁH 2 O, displays a distorted octahedral coordination geometry about the Co II atom, involving two 4-hydroxybenzoate anions, one 1,10-phenanthroline (phen) molecule and two water molecules. The face-to-face distance of 3.420 (5) A ˚betw
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.037 wR factor = 0.091 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.