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Di­aqua­bis(4-hydroxy­benzoato-κO)(1,10-phenanthroline-κ2N,N′)­cobalt(II) monohydrate

✍ Scribed by Su, Jian-Rong ;Gu, Jian-Ming ;Xu, Duan-Jun

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
276 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Co(C 7 H 5 O 3 ) 2 (C 12 H 8 N 2 )(H 2 O) 2 ]ÁH 2 O, displays a distorted octahedral coordination geometry about the Co II atom, involving two 4-hydroxybenzoate anions, one 1,10-phenanthroline (phen) molecule and two water molecules. The face-to-face distance of 3.420 (5) A ˚between partially overlapped parallel phen rings reflects astacking interaction between neighboring Co II complex molecules. A network of O-HÁ Á ÁO hydrogen bonds helps to stabilize the crystal packing.

📜 SIMILAR VOLUMES

Aqua­bis(4-formyl­benzoato-κO)(1,10-phen
Aqua­bis(4-formyl­benzoato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 253 KB

Single-crystal X-ray study T = 295 K Mean (C-C) = 0.003 A R factor = 0.033 wR factor = 0.088 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

μ-Aqua-bis­(μ-4-methyl­benzoato-κ2O:O′)b
μ-Aqua-bis­(μ-4-methyl­benzoato-κ2O:O′)bis[(4-methyl­benzoato-κO)(phenanthroline-κ2N,N′)cobalt(II)]
✍ Zhang, Bing-Yu ;Xu, Tu-Gen ;Xu, Duan-Jun 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 379 KB

The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral co