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(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(3-hydroxybenzoato-κ2O,O′)manganese(II) 2,9-dimethyl-1,10-phenanthroline dihydrate

✍ Scribed by Xuan, Xiao-peng ;Zhao, Pei-zheng ;Zhang, Shu-xia

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
590 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Mn(C~7~H~5~O~3~)~2~(C~14~H~12~N~2~)]·C~14~H~12~N~2~·2H~2~O, the Mn^II^ ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by O—H...O and O—H...N hydrogen bonds involving water molecules, the 3-hydroxybenzoate ligands and the uncoordinated dmphen molecules to form a three-dimensional network.

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✍ Xuan, Xiao-peng ;Zhao, Pei-zheng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 635 KB

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In the title compound, [Fe(NO 3 ) 2 (C 14 H 12 N 2 )(H 2 O)], the Fe atom is six-coordinated in an octahedral geometry by O and N atoms. The water molecules act as donors in O-HÁ Á ÁO hydrogen bonds, linking the molecules into chains along the c axis. The chains are connected into a three-dimensiona