In the title compound, [CuCl 2 (C 14 H 12 N 2 )(H 2 O)], there are two molecules in the asymmetric unit; both Cu atoms are fivecoordinate with a distorted trigonal-bipyramidal geometry. Molecules are linked into a three-dimensional network by O-HÁ Á ÁCl and C-HÁ Á ÁCl hydrogen bonds. The packing is
Aquadichloro(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)copper(II)
✍ Scribed by Lemoine, Pascale ;Viossat, Bernard ;Daran, Jean-Claude
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 271 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The crystal structure of the title compound, [CuCl 2 -(C 14 H 12 N 2 )(H 2 O)], previously reported by Preston & Kennard [J. Chem. Soc. A (1969). pp. 2955±2958], has been redetermined. The recognition of an inversion twin allowed a much better re®nement.
📜 SIMILAR VOLUMES
Benzoato-j 2 O,O 0 0 0 )chlorido(2,9-dimethyl-1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)
In the title compound, [Fe(NO 3 ) 2 (C 14 H 12 N 2 )(H 2 O)], the Fe atom is six-coordinated in an octahedral geometry by O and N atoms. The water molecules act as donors in O-HÁ Á ÁO hydrogen bonds, linking the molecules into chains along the c axis. The chains are connected into a three-dimensiona
In the title compound, [Mn(C~7~H~5~O~3~)~2~(C~14~H~12~N~2~)]·C~14~H~12~N~2~·2H~2~O, the Mn^II^ ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by O—H...O a
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.031 wR factor = 0.072 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.