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Aqua­(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)dinitratoiron(II)

✍ Scribed by Ding, Cai-Feng ;Yu, Yue-Qin ;Zhang, Mei-Ling ;Li, Xue-Mei ;Zhang, Shu-Sheng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
192 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Fe(NO 3 ) 2 (C 14 H 12 N 2 )(H 2 O)], the Fe atom is six-coordinated in an octahedral geometry by O and N atoms. The water molecules act as donors in O-HÁ Á ÁO hydrogen bonds, linking the molecules into chains along the c axis. The chains are connected into a three-dimensional framework by other O-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds. The packing is further stabilized by C-HÁ Á Á andinteractions.

📜 SIMILAR VOLUMES

Aqua­dichloro­(2,9-dimethyl-1,10-phenant
Aqua­dichloro­(2,9-dimethyl-1,10-phenanthroline-κ2N,N)copper(II)
✍ Ding, Cai-Feng ;Li, Xue-Mei ;Zhu, Mei ;Xu, Hong ;Zhang, Shu-Sheng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 212 KB

In the title compound, [CuCl 2 (C 14 H 12 N 2 )(H 2 O)], there are two molecules in the asymmetric unit; both Cu atoms are fivecoordinate with a distorted trigonal-bipyramidal geometry. Molecules are linked into a three-dimensional network by O-HÁ Á ÁCl and C-HÁ Á ÁCl hydrogen bonds. The packing is

Aqua­di­chloro(2,9-di­methyl-1,10-phenan
Aqua­di­chloro(2,9-di­methyl-1,10-phenanthroline-κ2N,N′)copper(II)
✍ Lemoine, Pascale ;Viossat, Bernard ;Daran, Jean-Claude 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 271 KB

The crystal structure of the title compound, [CuCl 2 -(C 14 H 12 N 2 )(H 2 O)], previously reported by Preston & Kennard [J. Chem. Soc. A (1969). pp. 2955±2958], has been redetermined. The recognition of an inversion twin allowed a much better re®nement.

(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′
(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(3-hydroxybenzoato-κ2O,O′)manganese(II) 2,9-dimethyl-1,10-phenanthroline dihydrate
✍ Xuan, Xiao-peng ;Zhao, Pei-zheng ;Zhang, Shu-xia 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 590 KB

In the title compound, [Mn(C~7~H~5~O~3~)~2~(C~14~H~12~N~2~)]·C~14~H~12~N~2~·2H~2~O, the Mn^II^ ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by O—H...O a

Diaqua(2,9-dimethyl-1,10-phenanthroline-
Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(3-hydroxybenzoato-κ2O,O′)nickel(II) nitrate
✍ Xuan, Xiao-peng ;Zhao, Pei-zheng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 635 KB

The asymmetric unit of the title compound, [Ni(C~7~H~5~O~3~)(C~14~H~12~N~2~)(H~2~O)~2~]NO~3~, comprises one half of the Ni^II^ complex cation and one half of the non-coordinated nitrate anion, as both the Ni atom and the N and one O atoms of the anion lie on twofold rotation axes. The Ni^2+^ cation