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Diaqua(2,9-dimethyl-1,10-phenanthroline-κ2N,N′)(3-hydroxybenzoato-κ2O,O′)nickel(II) nitrate

✍ Scribed by Xuan, Xiao-peng ;Zhao, Pei-zheng

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
635 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The asymmetric unit of the title compound, [Ni(C~7~H~5~O~3~)(C~14~H~12~N~2~)(H~2~O)~2~]NO~3~, comprises one half of the Ni^II^ complex cation and one half of the non-coordinated nitrate anion, as both the Ni atom and the N and one O atoms of the anion lie on twofold rotation axes. The Ni^2+^ cation is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two water molecules and a bidentate 3-hydroxybenzoate anion in a distorted octahedral environment. The OH group of the benzoate is disordered over two positions with equal occupancy. An extensive series of O—H...O hydrogen bonds leads to a supramolecular network structure.

📜 SIMILAR VOLUMES

(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′
(2,9-Dimethyl-1,10-phenanthroline-κ2N,N′)bis(3-hydroxybenzoato-κ2O,O′)manganese(II) 2,9-dimethyl-1,10-phenanthroline dihydrate
✍ Xuan, Xiao-peng ;Zhao, Pei-zheng ;Zhang, Shu-xia 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 590 KB

In the title compound, [Mn(C~7~H~5~O~3~)~2~(C~14~H~12~N~2~)]·C~14~H~12~N~2~·2H~2~O, the Mn^II^ ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two bidentate 3-hydroxybenzoate anions in a distorted octahedral environment. The structure is stabilized by O—H...O a

Di-μ2-acetato-1:2κ3O,O′:O;2:3κ3O:O,O′-te
Di-μ2-acetato-1:2κ3O,O′:O;2:3κ3O:O,O′-tetrakis(μ2-2-hydroxybenzoato)-1:2κ4O:O′;2:3κ4O:O′-bis(1,10-phenanthroline)-1κ2N,N′;3κ2N,N′-trizinc(II)
✍ Cai, Jin-Hua ;Xu, Ying-Hua ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 471 KB

Di-l 2 -acetato-1:2j 3 O,O 0 0 0 :O;2:3j 3 O:-O,O 0 0 0 -tetrakis(l 2 -2-hydroxybenzoato)-1:2j 4 O:O 0 0 0 ;2:3j 4 O:O 0 0 0 -bis(1,10-phenanthroline)-1j 2 N,N 0 0 0 ;3j 2 N,N 0 0 0 -trizinc(II)