Bis(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10-phenanthrolinej 2 N,N 0 0 0 )cadmium(II)-bis(l 2 -4-formylbenzoatoj 2 O:O 0 0 0 )bis[(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10phenanthroline-j 2 N,N 0 0 0 )cadmium(II)] (1/1
μ-Oxalato-κ2O1,O2:κ2O1′,O2′-bis[(3,5-dicarboxybenzoato-κ2O1,O1′)(1,10-phenanthroline-κ2N,N′)copper(II)]
✍ Scribed by Qin, Chao
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 182 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
)(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)]
📜 SIMILAR VOLUMES
l 2 -Oxalato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)] dinitrate dihydrate
In the title compound, [Cu(C~2~O~4~)(C~6~H~7~NO)~2~]~__n__~, the Cu^II^ atom is six-coordinated in a slightly deformed elongated octahedral arrangement and the 3-(hydroxymethyl)pyridine ligand, surprisingly, acts as a monodentate ligand coordinated only through the N atom of the pyridine ring. The o
Di-l 2 -acetato-1:2j 3 O,O 0 0 0 :O;2:3j 3 O:-O,O 0 0 0 -tetrakis(l 2 -2-hydroxybenzoato)-1:2j 4 O:O 0 0 0 ;2:3j 4 O:O 0 0 0 -bis(1,10-phenanthroline)-1j 2 N,N 0 0 0 ;3j 2 N,N 0 0 0 -trizinc(II)
l-Oxalato-1j 2 O,O 0 0 0 :2j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis(chloro{[1-(2pyridyl-jN)ethylidene]hydrazine-jN}copper(II)
In the title dimeric complex, [Cu~2~(C~2~O~4~)Cl~2~(C~12~H~8~N~2~)~2~], which lies on a crystallographic inversion center, the Cu^II^ ion is in a distorted trigonal–bipyramidal coordination geometry formed by two N atoms from a phen ligand, two O atoms from a bridging oxalate ligand and one Cl atom.