The polymeric structure of the title complex, [Cu(C~7~H~4~ClO~3~)~2~(C~6~H~7~NO)~2~]~__n__~, at 100 (2) K contains two-dimensional sheets parallel to the __ac__ plane. The Cu^II^ atom, lying on an inversion centre, has an octahedral coordination environment. It is bonded in a __trans__-square-planar
catena-Poly[[bis(2-nitrobenzoato-κO)copper(II)]di-μ-3-pyridylmethanol-κ2N,O;κ2O:N]
✍ Scribed by Stachová, Petra ;Valigura, Dušan ;Koman, Marian ;Glowiak, Tadeus
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 174 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Cu(C~2~O~4~)(C~6~H~7~NO)~2~]~__n__~, the Cu^II^ atom is six-coordinated in a slightly deformed elongated octahedral arrangement and the 3-(hydroxymethyl)pyridine ligand, surprisingly, acts as a monodentate ligand coordinated only through the N atom of the pyridine ring. The o
In the title complex, [Cu(C~8~H~6~NO~2~)~2~(C~6~H~7~NO)~2~(H~2~O)], the Cu^2+^ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of
)copper(II)]l-3,3 0 0 0 -dithiodipropionato-jO,O 0 0 0 :jO 0 0 00 0 0 ]