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Aqua­bis(3-pyridylacrylato)-κ2O,O′;κO-bis­(3-pyridylmethanol-κN)copper(II)

✍ Scribed by Moncol, Jan ;Segľa, Peter ;Jašková, Jana ;Fischer, Andreas ;Melník, Milan

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
297 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Cu(C~8~H~6~NO~2~)~2~(C~6~H~7~NO)~2~(H~2~O)], the Cu^2+^ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of 3-pyridylmethanol ligands and one water O atom. O—H...O and O–H...N hydrogen bonds result in the formation of a two-dimensional layer structure.

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