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Diaqua­bis{3-methyl-1-phenyl-4-[(E)-phen­yl(phenyl­iminio)meth­yl]-1H-pyrazol-5-olato-κ2O,N4}nickel(II) dimethyl sulfoxide disolvate

✍ Scribed by Cour, Agnete la ;Hazell, Alan


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
192 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Ni(C 23 H 18 N 3 O) 2 (H 2 O) 2 ]Á2C 2 H 6 OS, the Ni atom is octahedrally coordinated by two N atoms and two O atoms from two organic ligands and two water molecules which are cis to each other. The complex has crystallographic twofold rotation symmetry.


📜 SIMILAR VOLUMES


Bis{N-[(Z)-4-(3-methyl-5-oxo-1-phenyl-1H
✍ Ma, Rong-Ming ;Sun, Shao-Fa ;Bao, Feng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 227 KB

The Fe II atom in the title compound, [Fe(C 27 H 20 N 3 O) 2 ], is N,O-chelated by two deprotonated 3-methyl-4-[(1-naphthylamino)(phenyl)methylene]-1-phenyl-1H-pyrazol-5(4H)-one ligands in a severely distorted tetrahedral geometry.