𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis{N-[(Z)-4-(3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl­idene)(phen­yl)meth­yl]naphthyl­amido-κ2N,O}iron(II)

✍ Scribed by Ma, Rong-Ming ;Sun, Shao-Fa ;Bao, Feng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
227 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The Fe II atom in the title compound, [Fe(C 27 H 20 N 3 O) 2 ], is N,O-chelated by two deprotonated 3-methyl-4-[(1-naphthylamino)(phenyl)methylene]-1-phenyl-1H-pyrazol-5(4H)-one ligands in a severely distorted tetrahedral geometry.

📜 SIMILAR VOLUMES

Diaqua­bis{3-methyl-1-phenyl-4-[(E)-phen
Diaqua­bis{3-methyl-1-phenyl-4-[(E)-phen­yl(phenyl­iminio)meth­yl]-1H-pyrazol-5-olato-κ2O,N4}nickel(II) dimethyl sulfoxide disolvate
✍ Cour, Agnete la ;Hazell, Alan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 192 KB

In the title compound, [Ni(C 23 H 18 N 3 O) 2 (H 2 O) 2 ]Á2C 2 H 6 OS, the Ni atom is octahedrally coordinated by two N atoms and two O atoms from two organic ligands and two water molecules which are cis to each other. The complex has crystallographic twofold rotation symmetry.

Bis[2-(2,4-dioxopentan-3-yl­idene-κO)-1-
Bis[2-(2,4-dioxopentan-3-yl­idene-κO)-1-(4-methoxy­phen­yl)hydrazinato-κN1]copper(II)
✍ Mac-Leod-Carey, Desmond A. ;Bustos, Carlos ;Schott, Eduardo ;Alvarez-Thon, Luis 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 334 KB

Molecules in the title compound, [Cu(C~12~H~13~N~2~O~3~)~2~], are linked __via__ weak C—H...O and C—H...π(arene) interactions into a three-dimensional network. The Cu atom lies on an inversion centre, and therefore the asymmetric unit contains half a formula unit. The coordination geometry about the