Bis[2-(2,4-dioxopentan-3-ylidene-κO)-1-(4-methoxyphenyl)hydrazinato-κN1]copper(II)
✍ Scribed by Mac-Leod-Carey, Desmond A. ;Bustos, Carlos ;Schott, Eduardo ;Alvarez-Thon, Luis ;Fuentealba, Mauricio
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 334 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Molecules in the title compound, [Cu(C~12~H~13~N~2~O~3~)~2~], are linked via weak C—H...O and C—H...π(arene) interactions into a three-dimensional network. The Cu atom lies on an inversion centre, and therefore the asymmetric unit contains half a formula unit. The coordination geometry about the Cu atom can be described as tetragonally distorted octahedral.
📜 SIMILAR VOLUMES
Bis{N-[(Z)-(3-Methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)(phenyl)methyl]benzylamidoj 2 N,O}copper(II)
The Fe II atom in the title compound, [Fe(C 27 H 20 N 3 O) 2 ], is N,O-chelated by two deprotonated 3-methyl-4-[(1-naphthylamino)(phenyl)methylene]-1-phenyl-1H-pyrazol-5(4H)-one ligands in a severely distorted tetrahedral geometry.