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Bis[2-(2,4-dioxopentan-3-yl­idene-κO)-1-(4-methoxy­phen­yl)hydrazinato-κN1]copper(II)

✍ Scribed by Mac-Leod-Carey, Desmond A. ;Bustos, Carlos ;Schott, Eduardo ;Alvarez-Thon, Luis ;Fuentealba, Mauricio


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
334 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


Molecules in the title compound, [Cu(C~12~H~13~N~2~O~3~)~2~], are linked via weak C—H...O and C—H...π(arene) interactions into a three-dimensional network. The Cu atom lies on an inversion centre, and therefore the asymmetric unit contains half a formula unit. The coordination geometry about the Cu atom can be described as tetragonally distorted octahedral.


📜 SIMILAR VOLUMES


Bis{N-[(Z)-4-(3-methyl-5-oxo-1-phenyl-1H
✍ Ma, Rong-Ming ;Sun, Shao-Fa ;Bao, Feng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 227 KB

The Fe II atom in the title compound, [Fe(C 27 H 20 N 3 O) 2 ], is N,O-chelated by two deprotonated 3-methyl-4-[(1-naphthylamino)(phenyl)methylene]-1-phenyl-1H-pyrazol-5(4H)-one ligands in a severely distorted tetrahedral geometry.