Bis[4-(4-methoxyphenyl)-3-methyl-5-(2-pyridyl)-4H-1,2,4-triazole-κN1]bis(salicylato-κO)copper(II) methanol disolvate
✍ Scribed by Zhou, An-Yu ;Wang, Zuo-Xiang ;Lan, Yan ;Yuan, Lu-Tong ;Liu, Chun-Yi
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 160 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Molecules in the title compound, [Cu(C~12~H~13~N~2~O~3~)~2~], are linked __via__ weak C—H...O and C—H...π(arene) interactions into a three-dimensional network. The Cu atom lies on an inversion centre, and therefore the asymmetric unit contains half a formula unit. The coordination geometry about the
In the title compound, C~20~H~15~ClN~4~, the two benzene rings form dihedral angles of 30.95 (9) and 70.69 (6)° with the triazole ring, and the dihedral angle between the triazole and the pyridine rings is 43.38 (8)°. Intermolecular C—H...N hydrogen bonds are observed in the crystal structure.
In the title compound, C 15 H 14 N 4 OÁ2H 2 O, the 1,2,4-triazole, pyridine and benzene rings do not share a common plane. The crystal structure is stabilized by O-HÁ Á ÁN and O-HÁ Á ÁO intermolecular hydrogen-bond interactions.