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trans-Bis(hexa­fluoro­acetyl­acetonato-κ2O,O′)bis­[trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene-κN4]copper(II)

✍ Scribed by Granifo, Juan ;Vargas, Moisés ;Baggio, Ricardo

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
236 KB
Volume
62
Category
Article
ISSN
1600-5368

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📜 SIMILAR VOLUMES

catena-Poly[[copper(I)-di-μ-trans-1-(2-p
catena-Poly[[copper(I)-di-μ-trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene-κ2N2:N4;κ2N4:N2] tetra­fluoro­borate]
✍ Zhong, Kai-Long ;Lu, Wen-Jie 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 256 KB

In the title complex, {[Cu(C 12 H 10 N 2 ) 2 ]BF 4 } n , each copper(I) centre is tetrahedrally coordinated by N atoms from four bridging trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (TPPE) ligands. The ligands bridge adjacent copper(I) centres to form one-dimensional folded chains. Adjacent uniform ch

trans-Bis[(2E)-3-(N,N-dimethyl­amino)-1-
trans-Bis[(2E)-3-(N,N-dimethyl­amino)-1-(2-pyrid­yl)prop-2-en-1-one-κ2N,O]bis­(perchlorato-κO)cadmium(II)
✍ Hu, Tong-Liang ;Tian, Jin-Lei 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 171 KB

In the title compound, [Cd(ClO 4 ) 2 (C 10 H 12 N 2 O) 2 ], the Cd atom (site symmetry 1) is trans-coordinated by two N,O-bidentate chelating (2E)-3-(N,N-dimethylamino)-1-(2-pyridyl)prop-2en-1-one ligands, and by two O atoms from two perchlorate anions, in a slightly distorted octahedral geometry.