𝔖 Bobbio Scriptorium
✦   LIBER   ✦

catena-Poly[[copper(I)-di-μ-trans-1-(2-pyrid­yl)-2-(4-pyrid­yl)ethyl­ene-κ2N2:N4;κ2N4:N2] tetra­fluoro­borate]

✍ Scribed by Zhong, Kai-Long ;Lu, Wen-Jie

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
256 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title complex, {[Cu(C 12 H 10 N 2 ) 2 ]BF 4 } n , each copper(I) centre is tetrahedrally coordinated by N atoms from four bridging trans-1-(2-pyridyl)-2-(4-pyridyl)ethylene (TPPE) ligands. The ligands bridge adjacent copper(I) centres to form one-dimensional folded chains. Adjacent uniform chains are further interlinked into a three-dimensional framework through weak C-HÁ Á ÁF interactions.

📜 SIMILAR VOLUMES

catena-Poly[copper(I)-μ-2-(2-pyrid­yl)-1
catena-Poly[copper(I)-μ-2-(2-pyrid­yl)-1H-benzimidazolato-κ2N1:N3]
✍ Zeng, Ming-Hua ;Shen, Xing-Can ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 131 KB

Single-crystal X-ray study T = 295 K Mean () = 0.000 A Disorder in main residue R factor = 0.041 wR factor = 0.125 Data-to-parameter ratio = 9.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

catena-Poly­[[[μ-di-4-pyridyl­diazene-κ2
catena-Poly­[[[μ-di-4-pyridyl­diazene-κ2N4:N4′-bis­[(tri­phenyl­phosphine-κP)copper(I)]]-μ-pyridine-2-carb­aldehyde azine-κN2,N:N′,N2′] bis­(tetra­fluoro­borate)]
✍ Yu, Ming-Ming ;Fu, Wen-Fu ;Li, Zhan-Xian ;Yao, Zu-Fu ;Jia, Lin-Fang 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 224 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê Disorder in solvent or counterion R factor = 0.067 wR factor = 0.210 Data-to-parameter ratio = 13.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.