l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 -bis[(2,2 0 0 0 -bipyridinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
catena-Poly[[[μ-di-4-pyridyldiazene-κ2N4:N4′-bis[(triphenylphosphine-κP)copper(I)]]-μ-pyridine-2-carbaldehyde azine-κN2,N:N′,N2′] bis(tetrafluoroborate)]
✍ Scribed by Yu, Ming-Ming ;Fu, Wen-Fu ;Li, Zhan-Xian ;Yao, Zu-Fu ;Jia, Lin-Fang
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 224 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê Disorder in solvent or counterion R factor = 0.067 wR factor = 0.210 Data-to-parameter ratio = 13.4
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
l-4,4 0 0 0 -Bipyridine-j 2 N:N 0 0 0 )bis[(1,10-phenanthrolinej 2 N,N 0 0 0 )(triphenylphosphine-jP)copper(I)] bis(tetrafluoroborate)
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.045 wR factor = 0.133 Data-to-parameter ratio = 20.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, {[Ag(bpe)](OTf)} n (OTf = tri¯uoromethanesulfonate) or {[Ag(C 12 H 12 N 2 )](CF 3 O 3 S)} n , has been prepared from the reaction of 1,2-bis(4-pyridyl)ethane (bpe) and Ag(CF 3 SO 3 ) in MeCN/H 2 O. The Ag I atom is twocoordinate in a slightly distorted linear arrangement, and the