catena-Poly[[silver(I)-μ-1,2-bis(4-pyridyl)ethane-κ2N:N′] trifluoromethanesulfonate]
✍ Scribed by Li, Xiaoju ;Cao, Rong ;Sun, Daofeng ;Bi, Wenhua ;Wang, Yanqin ;Hong, Maochun
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 204 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, {Ag(bpe)} n (OTf = tri¯uoromethanesulfonate) or {[Ag(C 12 H 12 N 2 )](CF 3 O 3 S)} n , has been prepared from the reaction of 1,2-bis(4-pyridyl)ethane (bpe) and Ag(CF 3 SO 3 ) in MeCN/H 2 O. The Ag I atom is twocoordinate in a slightly distorted linear arrangement, and the bpe ligands link the Ag I atoms, in an anti fashion, into a onedimensional linear chain of alternating Ag I and bpe.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.003 A Ê R factor = 0.036 wR factor = 0.093 Data-to-parameter ratio = 27.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê Disorder in solvent or counterion R factor = 0.067 wR factor = 0.210 Data-to-parameter ratio = 13.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.045 wR factor = 0.133 Data-to-parameter ratio = 20.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.