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catena-Poly­[[silver(I)-μ-1,2-bis(4-pyridyl)­ethane-κ2N:N′] tri­fluoro­methane­sulfonate]

✍ Scribed by Li, Xiaoju ;Cao, Rong ;Sun, Daofeng ;Bi, Wenhua ;Wang, Yanqin ;Hong, Maochun


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
204 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, {Ag(bpe)} n (OTf = tri¯uoromethanesulfonate) or {[Ag(C 12 H 12 N 2 )](CF 3 O 3 S)} n , has been prepared from the reaction of 1,2-bis(4-pyridyl)ethane (bpe) and Ag(CF 3 SO 3 ) in MeCN/H 2 O. The Ag I atom is twocoordinate in a slightly distorted linear arrangement, and the bpe ligands link the Ag I atoms, in an anti fashion, into a onedimensional linear chain of alternating Ag I and bpe.


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