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Tetra­aqua­bis[2-(4-pyrid­yl)ethanesulfonato-κN]copper(II)

✍ Scribed by Zhang, Qi-Wei ;Wen, Yi-Hang

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
292 KB
Volume
62
Category
Article
ISSN
1600-5368

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The Mn atom in the title compound, [Mn(C~12~H~8~NO~2~)~2~(H~2~O)~4~], lies on a centre of inversion in an all-__trans__-N~2~O~4~Mn octahedron; as the 4-(4-pyridyl)benzoate ligands bind to Mn through the pyridyl N atom, the compound is formally a zwitterion. Hydrogen bonds link adjacent zwitterions i

Tetra­aqua­bis[5-(4-pyrid­yl)-1,3,4-oxad
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In the structure of the title compound, [Zn(C 7 H 4 N 3 OS) 2 -(H 2 O) 4 ]Á2H 2 O, the Zn II atom, located on an inversion centre, is coordinated by the pyridyl groups of two oxadiazole ligands and four water molecules. The packing is dominated by a three-dimensional system of hydrogen bonds.