Aquabis[3-ethyl-4-(4-methylphenyl)-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N,N′]copper(II) disalicylate dihydrate
✍ Scribed by Zhou, Bu-Gao ;Wang, Zuo-Xiang ;Qiu, Xiao-Yong ;Liu, Chun-Yi
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 125 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C~20~H~15~ClN~4~, the two benzene rings form dihedral angles of 30.95 (9) and 70.69 (6)° with the triazole ring, and the dihedral angle between the triazole and the pyridine rings is 43.38 (8)°. Intermolecular C—H...N hydrogen bonds are observed in the crystal structure.
In the title compound, C 15 H 14 N 4 OÁ2H 2 O, the 1,2,4-triazole, pyridine and benzene rings do not share a common plane. The crystal structure is stabilized by O-HÁ Á ÁN and O-HÁ Á ÁO intermolecular hydrogen-bond interactions.
In the structure of the title compound, [Zn(C 7 H 4 N 3 OS) 2 -(H 2 O) 4 ]Á2H 2 O, the Zn II atom, located on an inversion centre, is coordinated by the pyridyl groups of two oxadiazole ligands and four water molecules. The packing is dominated by a three-dimensional system of hydrogen bonds.