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Bis{N-[(Z)-(3-Methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)(phenyl)methyl]benzylamido-κ2N,O}copper(II)

✍ Scribed by Bao, Feng ;Feng, Juan ;Ng, Seik Weng

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 229 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805033805

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✦ Synopsis

Bis{N-[(Z)-(3-Methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)(phenyl)methyl]benzylamidoj 2 N,O}copper(II)

📜 SIMILAR VOLUMES

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The Fe II atom in the title compound, [Fe(C 27 H 20 N 3 O) 2 ], is N,O-chelated by two deprotonated 3-methyl-4-[(1-naphthylamino)(phenyl)methylene]-1-phenyl-1H-pyrazol-5(4H)-one ligands in a severely distorted tetrahedral geometry.

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In the mononuclear title complex, [Cu(C 18 H 14 Cl 2 N 3 O 2 ) 2 ], the Cu II atom is coordinated by two N atoms and two O atoms from the Schiff base ligands in a square-planar geometry, with a dihedral angle between the two chelate NCuO planes of 31.57 (3) . The Cu atom is located on a twofold axis

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In the title compound, [Ni(C 23 H 18 N 3 O) 2 (H 2 O) 2 ]Á2C 2 H 6 OS, the Ni atom is octahedrally coordinated by two N atoms and two O atoms from two organic ligands and two water molecules which are cis to each other. The complex has crystallographic twofold rotation symmetry.

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Bis[2-(2,4-dioxopentan-3-ylidene-κO)-1-(4-methoxyphenyl)hydrazinato-κN1]copper(II)

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Molecules in the title compound, [Cu(C~12~H~13~N~2~O~3~)~2~], are linked __via__ weak C—H...O and C—H...π(arene) interactions into a three-dimensional network. The Cu atom lies on an inversion centre, and therefore the asymmetric unit contains half a formula unit. The coordination geometry about the

Bis{N-[(Z)-(3-Methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)(phen­yl)meth­yl]benzyl­amido-κ2N,O}copper(II)

✦ Synopsis

Bis{N-[(Z)-(3-Methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)(phenyl)methyl]benzylamido-κ2N,O}copper(II)