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Bis{4-[(Z)-(2,4-dimethylphenylamino)phenylmethylene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ2N,O}(ethanol-κO)nickel(II)

✍ Scribed by Ma, Rong-Ming ;Sun, Shao-Fa ;Ng, Seik Weng

Publisher: International Union of Crystallography
Year: 2006
Tongue: English
Weight: 195 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680603844x

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✦ Synopsis

Bis{4-[(Z)-(2,4-dimethylphenylamino)phenylmethylene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-j 2 N,O}(ethanol-jO)nickel(II)

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The NH unit on the exocyclic C C double bond in the title compound, C 30 H 23 N 3 O, lies on the same side of the double bond as the carbonyl unit of the pyrazolonyl ring, and the two interact through an NÐHÁ Á ÁO hydrogen bond [2.671 (2) A Ê ].

Bis{4-[(Z)-(2,4-dimethyl­phenyl­amino)phenyl­methyl­ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ2N,O}(ethanol-κO)nickel(II)

✦ Synopsis

Bis{4-[(Z)-(2,4-dimethylphenylamino)phenylmethylene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κ2N,O}(ethanol-κO)nickel(II)