Benzoato-j 2 O,O 0 0 0 )chlorido(2,9-dimethyl-1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)
Di-μ-chlorido-bis[(2-anilinobenzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)copper(II)]
✍ Scribed by Jiang, Hui ;Ma, Jian-Fang ;Zhang, Wen-Li
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 804 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
Di-l-chlorido-bis[(2-anilinobenzoatoj 2 O,O 0 0 0 )(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)]
📜 SIMILAR VOLUMES
l 2 -Oxalato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)] dinitrate dihydrate
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h
In the title dimeric complex, [Cu~2~(C~2~O~4~)Cl~2~(C~12~H~8~N~2~)~2~], which lies on a crystallographic inversion center, the Cu^II^ ion is in a distorted trigonal–bipyramidal coordination geometry formed by two N atoms from a phen ligand, two O atoms from a bridging oxalate ligand and one Cl atom.