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Tetra­kis(μ-2-anilinobenzoato-κ2O:O′)bis­[(N,N-dimethyl­formamide-κO)copper(II)]

✍ Scribed by Wu, Ming-Yan ;Huang, You-Gui ;Wei, Wei ;Gao, Qiang ;Hong, Mao-Chun

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
298 KB
Volume
63
Category
Article
ISSN
1600-5368

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✍ Blewett, Gavin ;Esterhuysen, Catharine ;Bredenkamp, Martin W. ;Koch, Klaus R. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

The title compound, [Cu 2 (C 5 H 9 O 2 ) 4 (C 5 H 5 N) 2 ], consists of centrosymmetric binuclear cage units with four dimethylpropanoate bridges linking the two Cu centres [CuÁ Á ÁCu = 2.6229 (9) A ˚]. The square-pyramidal Cu coordination is completed by a pyridine N atom at the apical site. Astack

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The bis(4-ethylpyridine) adduct of dicopper(II) tetrabenzoate, [ Cu 2 (C 7 H 5 O 2 ) 4 (C 7 H 9 N) 2 ], has centrosymmetrically related square-pyramidal Cu atoms bridged by four benzoate ions; the heterocyclic ligands that occupy the apical sites are disordered.