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μ-Trithio­cyanurato-κ4N1,S2:N3,S4-bis­[(N,N,N′,N′′,N′′-penta­methyl­diethylenetriamine-κ3N,N′,N′′)zinc(II)] perchlorate monohydrate

✍ Scribed by Trávníček, Zdeněk ;Marek, Jaromír ;Čermáková, Šárka

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
206 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Zn~2~(C~3~N~3~S~3~)(C~9~H~23~N~3~)~2~]ClO~4~·H~2~O, the dinuclear Zn^II^ metal centres are bridged by a trithiocyanurate(3-) anion (ttc), with each centre having a distorted trigonal bipyramidal geometry and bonded to three diethylenetriamine N atoms, and an S and an N atom of ttc. The crystal structure is stabilized by O—H...O, O—H...S, C—H...S and C—H...O interactions connecting the cations, the ClO~4~
^−^ anions and the water molecules.

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