Di-μ-thiocyanato-κ2S:N;κ2N:S-bis{[N,N-dimethyl-N′-(2-pyridylmethylene-κN)ethane-1,2-diamine-κ2N,N′]nickel(II)} bis(perchlorate)

✍ Scribed by Diao, Yun-Peng

• Publisher: International Union of Crystallography
• Year: 2007
• Tongue: English
• Weight: 174 KB
• Volume: 63
• Category: Article
• ISSN: 1600-5368
• DOI: 10.1107/s1600536807019149

✦ Synopsis

In the title centrosymmetric dinuclear complex, [Ni 2 (NCS) 2 -(C 10 H 15 N 3 ) 2 ](ClO 4 ) 2 , each Ni II ion is pentacoordinated by the pyridine N, imine N, and amine N atoms of the Schiff base ligand, and by the terminal N and S atoms from two bridging thiocyanate ligands, forming a slightly distorted squarepyramidal coordination geometry.