In the title centrosymmetric dinuclear complex, [Ni 2 (NCS) 2 -(C 10 H 15 N 3 ) 2 ](ClO 4 ) 2 , each Ni II ion is pentacoordinated by the pyridine N, imine N, and amine N atoms of the Schiff base ligand, and by the terminal N and S atoms from two bridging thiocyanate ligands, forming a slightly dist
Bis{N-[bis(6-bromopyridin-2-yl)methylene-κN]ethane-1,2-diamine-κ2N,N′}nickel(II) bis(perchlorate)
✍ Scribed by Knight, James C. ;Amoroso, Angelo J. ;Prabaharan, Ravi ;Edwards, Peter G.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 173 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Bis{N-[bis(6-bromopyridin-2-yl)methylene-jN]ethane-1,2-diamine-j 2 N,N 0 0 0 }nickel(II) bis(perchlorate)
📜 SIMILAR VOLUMES
Bis [N-ethyl-N'-(pyridin-2-ylmethylene)ethane-1,2-diamine]nickel(II) bis(perchlorate) Z. Hong
The title complex, [Ni 2 Br 2 (C 2 H 8 N 2 ) 4 ]Br 2 , consists of two bromide anions and a complex dication. The dication is a centrosymmetric unit of two Ni atoms bridged unsymmetrically by two Br atoms. The Ni atoms are pseudo-octahedral, six-coordinate, with four N atoms from two 1,2-diaminoetha
l-Oxalato-j 4 O 1 ,O 2 :O 1 0 0 0 ,O 2 0 0 0 -bis{[N,N 0 0 0 -bis(pyridin-2-ylmethylene)propane-1,2-diamine-j 4 -N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]copper(II)} bis(perchlorate)