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(1,3-Diamino­propane-κ2N,N′)[tris­(2-amino­ethyl)amine-κ4N,N′,N′′,N′′′]nickel(II) bis­(perchlorate)

✍ Scribed by Lin, Yung-Chan ;Lu, Tian-Huey ;Li, Chang-Yao ;Liao, Fen-Ling ;Chung, Chung-Sun

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
367 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

Diaminopropane-j 2 N,N 0 0 0 )[tris(2-aminoethyl)amine-j 4 N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]nickel(II) bis(perchlorate)

📜 SIMILAR VOLUMES

[Tris­(2-amino­ethyl)amine-κ3N,N′,N′′,N′
[Tris­(2-amino­ethyl)amine-κ3N,N′,N′′,N′′′](l-tyrosinato-κ2N,O)nickel(II) iodide dihydrate
✍ Pei, Yamei ;Wang, Li 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 356 KB

In the title compound, [Ni(C~9~H~10~NO~3~)(C~6~H~18~N~4~)]I·2H~2~O, the Ni^II^ atom is in a slightly distorted octahedral coordination environment. In the crystal structure, extensive hydrogen bonding links molecules into a three-dimensional network.

[N,N,N′-Tris(3-amino­prop­yl)ethyl­enedi
[N,N,N′-Tris(3-amino­prop­yl)ethyl­enediamine-κ5N]nickel bis­(perchlorate)
✍ Xu, Tong-Tao ;Xu, Xing-You ;Wang, Da-Qi ;Gao, Jian ;Lu, Lu-De 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 243 KB

The asymmetric unit of the title complex, [Ni(C~11~H~29~N~5~)](ClO~4~)~2~, consists of an [Ni(C~11~H~29~N~5~)]^2+^ cation and two uncoordinated perchlorate anions. The Ni^II^ atom is five-coordinated in a slightly distorted square-pyramidal geometry, with four of the N atoms forming the basal plane

Di-μ-azido-κ4N:N-bis­{(azido-κN)[N,N-bis
Di-μ-azido-κ4N:N-bis­{(azido-κN)[N,N-bis­(2-pyridylmethyl-κN)ethyl­amine]manganese(II)}
✍ Qian, Jing ;Gu, Wu ;Yan, Shi-Ping ;Liao, Dai-Zheng ;Cheng, Peng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 122 KB

The title compound, [Mn~2~(N~3~)~4~(C~14~H~17~N~3~)~2~], comprises two [Mn(bpea)(N~3~)]^+^ fragments [where bpea is the tridentate ligand __N__,__N__-bis(2-pyridylmethyl)ethylamine] bridged by two azide anions to form a centrosymmetric dinuclear complex. The coordination environment around the Mn^II