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μ-4,4′-Bipyridine-κ2N:N′-bis­{[N-(2-amino­ethyl)-1,3-propyl­diamine-κ3N,N′,N′′]aqua­copper(II)} tetra­kis(perchlorate)

✍ Scribed by Zhang, Zhen-Ming ;Wang, Da-Qi ;Jian, Gao ;Li, Shuan


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
172 KB
Volume
62
Category
Article
ISSN
1600-5368

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Bis(μ-azido-κ2N:N)bis­[azido­(N,N-dimeth
✍ Cai, Wen-Xuan ;Su, Hong ;Feng, Yun-Long 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 136 KB

The title complex, [Cu 2 (N 3 ) 4 (C 5 H 14 N 2 ) 2 ], is a centrosymmetric dimer in which each Cu atom is coordinated by five N atoms from three azide anions and one N,N-dimethyl-1,3-propylenediamine molecule in a distorted square-pyramidal geometry; the CuÁ Á ÁCu distance is 3.416 (1) A ˚.