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Bis(μ-azido-κ2N:N)bis­[azido­(N,N-dimethyl-1,3-propyl­enediamine-κ2N,N)copper(II)]

✍ Scribed by Cai, Wen-Xuan ;Su, Hong ;Feng, Yun-Long

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
136 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Cu 2 (N 3 ) 4 (C 5 H 14 N 2 ) 2 ], is a centrosymmetric dimer in which each Cu atom is coordinated by five N atoms from three azide anions and one N,N-dimethyl-1,3-propylenediamine molecule in a distorted square-pyramidal geometry; the CuÁ Á ÁCu distance is 3.416 (1) A ˚.

📜 SIMILAR VOLUMES

Di-μ-azido-κ4N:N-bis­{(azido-κN)[N,N-bis
Di-μ-azido-κ4N:N-bis­{(azido-κN)[N,N-bis­(2-pyridylmethyl-κN)ethyl­amine]manganese(II)}
✍ Qian, Jing ;Gu, Wu ;Yan, Shi-Ping ;Liao, Dai-Zheng ;Cheng, Peng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 122 KB

The title compound, [Mn~2~(N~3~)~4~(C~14~H~17~N~3~)~2~], comprises two [Mn(bpea)(N~3~)]^+^ fragments [where bpea is the tridentate ligand __N__,__N__-bis(2-pyridylmethyl)ethylamine] bridged by two azide anions to form a centrosymmetric dinuclear complex. The coordination environment around the Mn^II

Bis(μ-azido-κ2N,N)bis({2-[3-(dimethylami
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✍ Hou, Hai-Yun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 405 KB

The title complex, [Cu 2 (N 3 ) 2 (C 12 H 16 N 3 O 3 ) 2 ], is an azidebridged dinuclear copper(II) complex. There is a crystallographic inversion centre at the mid-point of the CuÁ Á ÁCu vector. Each Cu atom is coordinated by one O and two N atoms of one Schiff base ligand and two bridging N atoms

Di-μ-thiocyanato-κ2S:N;κ2N:S-bis{[N,N-di
Di-μ-thiocyanato-κ2S:N;κ2N:S-bis{[N,N-dimethyl-N′-(2-pyridylmethylene-κN)ethane-1,2-diamine-κ2N,N′]nickel(II)} bis(perchlorate)
✍ Diao, Yun-Peng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 174 KB

In the title centrosymmetric dinuclear complex, [Ni 2 (NCS) 2 -(C 10 H 15 N 3 ) 2 ](ClO 4 ) 2 , each Ni II ion is pentacoordinated by the pyridine N, imine N, and amine N atoms of the Schiff base ligand, and by the terminal N and S atoms from two bridging thiocyanate ligands, forming a slightly dist