✦ LIBER ✦

Bis(μ-azido-κ2N,N)bis({2-[3-(dimethylamino)propyliminomethyl]-4-nitrophenolato-κ3O,N,N′}copper(II))

✍ Scribed by Hou, Hai-Yun

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 405 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807023902

No coin nor oath required. For personal study only.

✦ Synopsis

The title complex, [Cu 2 (N 3 ) 2 (C 12 H 16 N 3 O 3 ) 2 ], is an azidebridged dinuclear copper(II) complex. There is a crystallographic inversion centre at the mid-point of the CuÁ Á ÁCu vector. Each Cu atom is coordinated by one O and two N atoms of one Schiff base ligand and two bridging N atoms from two azide ligands, forming a trigonal-bipyramidal geometry. The CuÁ Á ÁCu distance is 3.327 (2) A ˚.

📜 SIMILAR VOLUMES

Acetonitrile{2-[3-(dimethylamino)propyli

Acetonitrile{2-[3-(dimethylamino)propyliminomethyl]-4-nitrophenolato-κ3N,N′,O}(thiocyanato-κN)copper(II)

✍ Ye, Li-Juan ;You, Zhonglu 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 462 KB

Bis(μ-azido-κ2N:N)bis[azido(N,N-dimeth

Bis(μ-azido-κ2N:N)bis[azido(N,N-dimethyl-1,3-propylenediamine-κ2N,N)copper(II)]

✍ Cai, Wen-Xuan ;Su, Hong ;Feng, Yun-Long 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 136 KB

The title complex, [Cu 2 (N 3 ) 4 (C 5 H 14 N 2 ) 2 ], is a centrosymmetric dimer in which each Cu atom is coordinated by five N atoms from three azide anions and one N,N-dimethyl-1,3-propylenediamine molecule in a distorted square-pyramidal geometry; the CuÁ Á ÁCu distance is 3.416 (1) A ˚.

Bis(μ-2-aminoethanesulfonato)-κ3N,O:O′;

Bis(μ-2-aminoethanesulfonato)-κ3N,O:O′;κ3O′:N,O-bis[(bipyridine-κ2N,N′)(perchlorato-κO)copper(II)]

✍ Cai, Jin-Hua ;Jiang, Yi-Min ;Wang, Xiu-Jian ;Liu, Zhi-Min 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 312 KB

Di-μ-azido-κ4N:N-bis{(azido-κN)[N,N-bis

Di-μ-azido-κ4N:N-bis{(azido-κN)[N,N-bis(2-pyridylmethyl-κN)ethylamine]manganese(II)}

✍ Qian, Jing ;Gu, Wu ;Yan, Shi-Ping ;Liao, Dai-Zheng ;Cheng, Peng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 122 KB

The title compound, [Mn~2~(N~3~)~4~(C~14~H~17~N~3~)~2~], comprises two [Mn(bpea)(N~3~)]^+^ fragments [where bpea is the tridentate ligand __N__,__N__-bis(2-pyridylmethyl)ethylamine] bridged by two azide anions to form a centrosymmetric dinuclear complex. The coordination environment around the Mn^II

trans-Bis{2-[3-(cyclohexylamino)propylim

trans-Bis{2-[3-(cyclohexylamino)propyliminomethyl]phenolato-κ2N,O}bis(thiocyanato-κN)iron(II)

✍ Chen, Kun ;Zhang, Ying-Lao ;Feng, Ming-Qian ;Liu, Chang-Hong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 705 KB

The title complex, [Fe(NCS) 2 (C 32 H 46 N 4 O 2 ) 2 ], is a mononuclear iron(II) complex with a distorted octahedral coordination geometry and the central Fe 2+ ion, located on an inversion centre, is coordinated by four N atoms and two O atoms from two Schiff-base ligands and two thiocyanate anion

Bis[μ2-N,N′-bis(2-oxidobenzyl)propane-1,

Bis[μ2-N,N′-bis(2-oxidobenzyl)propane-1,3-diamine]-1κ4O,N,N′,O′:2κ2O,O′;2κ2O,O′:3κ4O,N,N′,O′-bis(N,N′-dimethylformamide)-1κO,3κO-di-μ2-acetato-1:2κ2O:O′;2:3κ2O:O′-dinickel(II)zinc(II)

✍ Tatar Yıldırım, Leyla ;Ergun, Ümit 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 931 KB