The title complex, [Cu 2 (N 3 ) 2 (C 12 H 16 N 3 O 3 ) 2 ], is an azidebridged dinuclear copper(II) complex. There is a crystallographic inversion centre at the mid-point of the CuÁ Á ÁCu vector. Each Cu atom is coordinated by one O and two N atoms of one Schiff base ligand and two bridging N atoms
Acetonitrile{2-[3-(dimethylamino)propyliminomethyl]-4-nitrophenolato-κ3N,N′,O}(thiocyanato-κN)copper(II)
✍ Scribed by Ye, Li-Juan ;You, Zhonglu
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 462 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title complex, [Fe(NCS) 2 (C 32 H 46 N 4 O 2 ) 2 ], is a mononuclear iron(II) complex with a distorted octahedral coordination geometry and the central Fe 2+ ion, located on an inversion centre, is coordinated by four N atoms and two O atoms from two Schiff-base ligands and two thiocyanate anion
In the title compound, [Cu(C 11 H 14 BrN 2 O)(NCS)], the Cu atom is four-coordinated by the NNO donor set of the Schiff base ligand and by the terminal N atom of the thiocyanate anion, forming a square-planar geometry. An N-HÁ Á ÁS hydrogen bond helps to establish the packing.