(1,3-Propanediamine-κ2N,N′)bis(thiocyanato-κN)copper(II)
✍ Scribed by You, Zhong-Lu ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 596 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The Zn atom of the title complex, [Zn(NCS)~2~(C~7~H~8~N~4~O)~2~(H~2~O)~2~] or [Zn(SCN)~2~(H-Pysc)~2~(H~2~O)~2~] [H-Pysc = __N__-aminocarbonyl-__N__′-(3-pyridylmethylene)hydrazine], derived from the condensation of pyridine-3-carbaldehyde and semicarbazone, is located at a crystallographic centre of
In the title compound, [Cu(C 11 H 14 BrN 2 O)(NCS)], the Cu atom is four-coordinated by the NNO donor set of the Schiff base ligand and by the terminal N atom of the thiocyanate anion, forming a square-planar geometry. An N-HÁ Á ÁS hydrogen bond helps to establish the packing.