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{4-Bromo-2-[2-(ethylamino)ethyliminomethyl]phenolato-κ3N,N′,O}(thiocyanato-κN)copper(II)

✍ Scribed by Zhou, Zhi ;Tang, Rui-Ren

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
306 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cu(C 11 H 14 BrN 2 O)(NCS)], the Cu atom is four-coordinated by the NNO donor set of the Schiff base ligand and by the terminal N atom of the thiocyanate anion, forming a square-planar geometry. An N-HÁ Á ÁS hydrogen bond helps to establish the packing.

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Di-μ-thiocyanato-κ4N:N-bis({2-[2-(methyl
Di-μ-thiocyanato-κ4N:N-bis({2-[2-(methylamino)ethyliminomethyl]phenolato}copper(II))
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The asymmetric unit of the title compound, [Cu 2 (NCS) 2 -(C 10 H 13 N 2 O) 2 ], contains one-half of the centrosymmetric dinuclear complex, which exhibits a CuÁ Á ÁCu separation of 3.255 (2) A ˚. In the complex, each Cu II ion is pentacoordinated in a square-pyramidal geometry. The basal plane is f

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The title complex, [Fe(NCS) 2 (C 32 H 46 N 4 O 2 ) 2 ], is a mononuclear iron(II) complex with a distorted octahedral coordination geometry and the central Fe 2+ ion, located on an inversion centre, is coordinated by four N atoms and two O atoms from two Schiff-base ligands and two thiocyanate anion